Raw NCAs are encrypted.
The only known section which is not encrypted in the raw NCA is the logo section, when the NCA includes that section.
Logo section
Contains the raw FS for the logo FS, see here for mounted-FS contents.
There's 0x4000-bytes of zeros at rawnca+0x4000, then the actual data starts at absolute offset 0x8000, which is the PFS0.
PFS0
This is the FS which has magicnum "PFS0" at header+0.